The NTFS permissions on the SSL folder (C:\ProgramData\VMware\VMware VirtualCenter\SSL) are normally inherited from the parent folder.
There could be other permission that come from other components. For example some backup tools run under a service account that also needs some access.
What do you want to check in fact ?
Is there a file that contains the permissions that should be there ?
Wouldn't it be easier to activate auditing on that folder (success and failure) ?
In that case you detect any changes from the security eventlog ?